Reactions of metals with dilute acid
1. General Behavior of Metals with Dilute Acids
When a metal reacts with a dilute acid, it usually produces:
A salt (depending on the acid)
Hydrogen gas (H₂)
General equation: Metal + Acid → Metal Salt + Hydrogen gas.
2. Why These Reactions Occur
Metals that are more reactive than hydrogen in the reactivity series can push hydrogen out of the acid.
This is known as a displacement reaction.
The reaction often releases energy, making the container warm.
3. Factors Affecting the Reaction
Position in reactivity series:
Higher → faster reaction
Lower → slower or no reaction
Surface area:
Powdered metal reacts faster than a lump.
Concentration of acid:
More concentrated → faster reaction.
Temperature:
Higher temperature → increased reaction rate.
4. Examples of Metal–Acid Reactions
4.1 Magnesium (very reactive)
Reaction: Mg + 2HCl → MgCl₂ + H₂
Observations:
Very fast bubbling
Heat released
Magnesium disappears quickly
4.2 Zinc (moderately reactive)
Reaction:Zn + H₂SO₄ → ZnSO₄ + H₂
Observations:
Steady stream of bubbles
Reaction is neither too slow nor too fast
4.3 Iron (less reactive)
Reaction:Fe + 2HCl → FeCl₂ + H₂
Observations:
Slow fizzing
Iron takes longer to dissolve
Slight warming of the solution
5. Metals That Do NOT React with Dilute Acids
These metals are below hydrogen in the reactivity series:
Copper (Cu)
Silver (Ag)
Gold (Au)
Platinum (Pt)
Reason:They are too unreactive to displace hydrogen from acids.
6. Identifying Hydrogen Gas
You can test for hydrogen using:
“Pop test”: Bring a burning splint near the gas → it makes a small pop sound.
7. Safety Notes
Hydrogen is flammable → avoid open flames near reaction.
Use dilute acids to avoid dangerous heat or rapid reactions.
Wear goggles and gloves in a laboratory.





