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Reactions of metals with dilute acid

1. General Behavior of Metals with Dilute Acids



  • When a metal reacts with a dilute acid, it usually produces:

    • A salt (depending on the acid)

    • Hydrogen gas (H₂)

  • General equation: Metal + Acid → Metal Salt + Hydrogen gas.




2. Why These Reactions Occur



  • Metals that are more reactive than hydrogen in the reactivity series can push hydrogen out of the acid.

  • This is known as a displacement reaction.

  • The reaction often releases energy, making the container warm.



3. Factors Affecting the Reaction



  • Position in reactivity series:

    • Higher → faster reaction

    • Lower → slower or no reaction

  • Surface area:

    • Powdered metal reacts faster than a lump.

  • Concentration of acid:

    • More concentrated → faster reaction.

  • Temperature:

    • Higher temperature → increased reaction rate.



4. Examples of Metal–Acid Reactions


4.1 Magnesium (very reactive)


  • Reaction: Mg + 2HCl → MgCl₂ + H₂

  • Observations:

    • Very fast bubbling

    • Heat released

    • Magnesium disappears quickly



4.2 Zinc (moderately reactive)

  • Reaction:Zn + H₂SO₄ → ZnSO₄ + H₂

  • Observations:

    • Steady stream of bubbles

    • Reaction is neither too slow nor too fast



4.3 Iron (less reactive)

  • Reaction:Fe + 2HCl → FeCl₂ + H₂

  • Observations:

    • Slow fizzing

    • Iron takes longer to dissolve

    • Slight warming of the solution



5. Metals That Do NOT React with Dilute Acids

These metals are below hydrogen in the reactivity series:

  • Copper (Cu)

  • Silver (Ag)

  • Gold (Au)

  • Platinum (Pt)

Reason:They are too unreactive to displace hydrogen from acids.



6. Identifying Hydrogen Gas

You can test for hydrogen using:

  • “Pop test”: Bring a burning splint near the gas → it makes a small pop sound.



7. Safety Notes

  • Hydrogen is flammable → avoid open flames near reaction.

  • Use dilute acids to avoid dangerous heat or rapid reactions.

  • Wear goggles and gloves in a laboratory.



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